Asymmetric primitive-model electrolytes: Debye-Hückel theory, criticality, and energy bounds
نویسندگان
چکیده
منابع مشابه
Asymmetric primitive-model electrolytes: Debye-Hückel theory, criticality, and energy bounds.
Debye-Hückel (DH) theory is extended to treat two-component size- and charge-asymmetric primitive models, focusing primarily on the 1:1 additive hard-sphere electrolyte with, say, negative ion diameters a(--) larger than the positive ion diameters a(++). The treatment highlights the crucial importance of the charge-unbalanced "border zones" around each ion into which other ions of only one spec...
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Monte Carlo (MC) simulations have been performed for primitive model electrolytes for moderate Bjerrum parameters (B = 1, B = 1.546 and a few with B = 1.681) and values of m in t he range ca. 0.015-0.45. Emphasis has been laid on very dilute systems. Several millions of configurations have been used, and the number of ions in each simulation (N) was varied between N = 32 and N = 1000 (N = 1728 ...
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ژورنال
عنوان ژورنال: Physical Review E
سال: 2001
ISSN: 1063-651X,1095-3787
DOI: 10.1103/physreve.64.011206